IB 5355 then LA 5758 at Barcelona
Milan → Barcelona → Rome
Timetable, Barcelona time
14:55IB 5355 from Milan at the gatealso LL 5355, VY 6043
14:40LA 5758 to Rome leaves the gate
23 h 45 apart on the timetable, overnight
LA 5758 leaves 23 h 45 after IB 5355 arrives on the timetable: more than half a day, so not a connection we count.