QR 3630 then FR 6597 at Barcelona
Firenze → Barcelona → Manchester
Timetable, Barcelona time
14:55QR 3630 from Firenze at the gatealso IB 5375, LL 5375, VY 6075
10:25FR 6597 to Manchester leaves the gate
19 h 30 apart on the timetable, overnight
FR 6597 leaves 19 h 30 after QR 3630 arrives on the timetable: more than half a day, so not a connection we count.