IB 5375 then QR 3614 at Barcelona
Firenze → Barcelona → Berlin
Timetable, Barcelona time
17:55IB 5375 from Firenze at the gatealso LL 5375, VY 6075
14:50QR 3614 to Berlin leaves the gate
20 h 55 apart on the timetable, overnight
QR 3614 leaves 20 h 55 after IB 5375 arrives on the timetable: more than half a day, so not a connection we count.