IB 5387 then FR 133 at Barcelona
Bologna → Barcelona → Berlin
Timetable, Barcelona time
14:20IB 5387 from Bologna at the gatealso LL 5387
11:50FR 133 to Berlin leaves the gate
21 h 30 apart on the timetable, overnight
FR 133 leaves 21 h 30 after IB 5387 arrives on the timetable: more than half a day, so not a connection we count.