IB 5465 then VY 6012 at Barcelona
Lyon → Barcelona → Rome
Timetable, Barcelona time
17:40IB 5465 from Lyon at the gate
14:40VY 6012 to Rome leaves the gate
21 h apart on the timetable, overnight
VY 6012 leaves 21 h after IB 5465 arrives on the timetable: more than half a day, so not a connection we count.