KL 1513 then EC 7173 at Barcelona
Amsterdam → Barcelona → Berlin
Timetable, Barcelona time
12:15KL 1513 from Amsterdam at the gatealso DL 9186
07:20EC 7173 to Berlin leaves the gate
19 h 05 apart on the timetable, overnight
EC 7173 leaves 19 h 05 after KL 1513 arrives on the timetable: more than half a day, so not a connection we count.