KL 1513 then FR 7543 at Barcelona
Amsterdam → Barcelona → Manchester
Timetable, Barcelona time
12:15KL 1513 from Amsterdam at the gatealso DL 9186
11:35FR 7543 to Manchester leaves the gate
23 h 20 apart on the timetable, overnight
FR 7543 leaves 23 h 20 after KL 1513 arrives on the timetable: more than half a day, so not a connection we count.