LA 5742 then FR 7539 at Barcelona
Amsterdam → Barcelona → Milan
Timetable, Barcelona time
09:20LA 5742 from Amsterdam at the gate
08:40FR 7539 to Milan leaves the gate
23 h 20 apart on the timetable, overnight
FR 7539 leaves 23 h 20 after LA 5742 arrives on the timetable: more than half a day, so not a connection we count.