LA 5745 then VY 1220 at Barcelona
Rome → Barcelona → Valladolid
Timetable, Barcelona time
01:25LA 5745 from Rome at the gate
16:05VY 1220 to Valladolid leaves the gatealso IB 5472
14 h 40 apart on the timetable
VY 1220 leaves 14 h 40 after LA 5745 arrives on the timetable: more than half a day, so not a connection we count.