LA 5850 then EC 7173 at Barcelona
Alicante → Barcelona → Berlin
Timetable, Barcelona time
08:05LA 5850 from Alicante at the gate
07:20EC 7173 to Berlin leaves the gate
23 h 15 apart on the timetable, overnight
EC 7173 leaves 23 h 15 after LA 5850 arrives on the timetable: more than half a day, so not a connection we count.