LL 5003 then FR 149 at Barcelona
Amsterdam → Barcelona → Berlin
Timetable, Barcelona time
17:10LL 5003 from Amsterdam at the gate
14:20FR 149 to Berlin leaves the gate
21 h 10 apart on the timetable, overnight
FR 149 leaves 21 h 10 after LL 5003 arrives on the timetable: more than half a day, so not a connection we count.