LL 5003 then FR 3180 at Barcelona
Amsterdam → Barcelona → Rome
Timetable, Barcelona time
17:10LL 5003 from Amsterdam at the gate
06:05FR 3180 to Rome leaves the gate
12 h 55 apart on the timetable, overnight
FR 3180 leaves 12 h 55 after LL 5003 arrives on the timetable: more than half a day, so not a connection we count.