LL 5003 then FR 867 at Barcelona
Amsterdam → Barcelona → Venezia
Timetable, Barcelona time
17:10LL 5003 from Amsterdam at the gate
09:45FR 867 to Venezia leaves the gate
16 h 35 apart on the timetable, overnight
FR 867 leaves 16 h 35 after LL 5003 arrives on the timetable: more than half a day, so not a connection we count.