LL 5023 then FR 3180 at Barcelona
Athens → Barcelona → Rome
Timetable, Barcelona time
14:05LL 5023 from Athens at the gate
06:05FR 3180 to Rome leaves the gate
16 h apart on the timetable, overnight
FR 3180 leaves 16 h after LL 5023 arrives on the timetable: more than half a day, so not a connection we count.