LL 5029 then EC 7107 at Barcelona
Berlin → Barcelona → Geneva
Timetable, Barcelona time
13:10LL 5029 from Berlin at the gate
10:30EC 7107 to Geneva leaves the gate
21 h 20 apart on the timetable, overnight
EC 7107 leaves 21 h 20 after LL 5029 arrives on the timetable: more than half a day, so not a connection we count.