LL 5029 then FR 3140 at Barcelona
Berlin → Barcelona → Luxembourg
Timetable, Barcelona time
13:10LL 5029 from Berlin at the gate
06:25FR 3140 to Luxembourg leaves the gate
17 h 15 apart on the timetable, overnight
FR 3140 leaves 17 h 15 after LL 5029 arrives on the timetable: more than half a day, so not a connection we count.