LL 5029 then FR 3180 at Barcelona
Berlin → Barcelona → Rome
Timetable, Barcelona time
13:10LL 5029 from Berlin at the gate
05:55FR 3180 to Rome leaves the gate
16 h 45 apart on the timetable, overnight
FR 3180 leaves 16 h 45 after LL 5029 arrives on the timetable: more than half a day, so not a connection we count.