LL 5029 then FR 7543 at Barcelona
Berlin → Barcelona → Manchester
Timetable, Barcelona time
13:20LL 5029 from Berlin at the gate
11:35FR 7543 to Manchester leaves the gate
22 h 15 apart on the timetable, overnight
FR 7543 leaves 22 h 15 after LL 5029 arrives on the timetable: more than half a day, so not a connection we count.