LL 5029 then LL 5122 at Barcelona
Berlin → Barcelona → Munich
Timetable, Barcelona time
13:20LL 5029 from Berlin at the gate
12:55LL 5122 to Munich leaves the gate
23 h 35 apart on the timetable, overnight
LL 5122 leaves 23 h 35 after LL 5029 arrives on the timetable: more than half a day, so not a connection we count.