LL 5087 then QR 3577 at Barcelona
Culleredo → Barcelona → Berlin
Timetable, Barcelona time
00:05LL 5087 from Culleredo at the gate
14:00QR 3577 to Berlin leaves the gate
13 h 55 apart on the timetable
QR 3577 leaves 13 h 55 after LL 5087 arrives on the timetable: more than half a day, so not a connection we count.