LL 5113 then FR 149 at Barcelona
Lisbon → Barcelona → Berlin
Timetable, Barcelona time
17:05LL 5113 from Lisbon at the gate
14:20FR 149 to Berlin leaves the gate
21 h 15 apart on the timetable, overnight
FR 149 leaves 21 h 15 after LL 5113 arrives on the timetable: more than half a day, so not a connection we count.