LL 5129 then FR 5216 at Barcelona
Alicante → Barcelona → Bologna
Timetable, Barcelona time
11:00LL 5129 from Alicante at the gate
10:25FR 5216 to Bologna leaves the gate
23 h 25 apart on the timetable, overnight
FR 5216 leaves 23 h 25 after LL 5129 arrives on the timetable: more than half a day, so not a connection we count.