LL 5325 then FR 2507 at Barcelona
Palma de Mallorca → Barcelona → Cologne
Timetable, Barcelona time
18:10LL 5325 from Palma de Mallorca at the gate
06:20FR 2507 to Cologne leaves the gate
12 h 10 apart on the timetable, overnight
FR 2507 leaves 12 h 10 after LL 5325 arrives on the timetable: more than half a day, so not a connection we count.