LL 5457 then EC 7107 at Barcelona
Vigo → Barcelona → Geneva
Timetable, Barcelona time
11:45LL 5457 from Vigo at the gate
10:30EC 7107 to Geneva leaves the gate
22 h 45 apart on the timetable, overnight
EC 7107 leaves 22 h 45 after LL 5457 arrives on the timetable: more than half a day, so not a connection we count.