LL 5475 then FR 133 at Barcelona
Nice → Barcelona → Berlin
Timetable, Barcelona time
10:15LL 5475 from Nice at the gate
07:40FR 133 to Berlin leaves the gate
21 h 25 apart on the timetable, overnight
FR 133 leaves 21 h 25 after LL 5475 arrives on the timetable: more than half a day, so not a connection we count.