LL 5501 then QR 3577 at Barcelona
Vigo → Barcelona → Berlin
Timetable, Barcelona time
01:40LL 5501 from Vigo at the gate
14:00QR 3577 to Berlin leaves the gate
12 h 20 apart on the timetable
QR 3577 leaves 12 h 20 after LL 5501 arrives on the timetable: more than half a day, so not a connection we count.