QR 137 then FR 6597 at Barcelona
Doha → Barcelona → Manchester
Timetable, Barcelona time
07:05QR 137 from Doha at the gate
21:40FR 6597 to Manchester leaves the gate
14 h 35 apart on the timetable
FR 6597 leaves 14 h 35 after QR 137 arrives on the timetable: more than half a day, so not a connection we count.