QR 3502 then FR 133 at Barcelona
Málaga → Barcelona → Berlin
Timetable, Barcelona time
21:10QR 3502 from Málaga at the gate
18:50FR 133 to Berlin leaves the gate
21 h 40 apart on the timetable, overnight
FR 133 leaves 21 h 40 after QR 3502 arrives on the timetable: more than half a day, so not a connection we count.