QR 3536 then FR 6597 at Barcelona
Bilbao → Barcelona → Manchester
Timetable, Barcelona time
11:05QR 3536 from Bilbao at the gate
10:25FR 6597 to Manchester leaves the gate
23 h 20 apart on the timetable, overnight
FR 6597 leaves 23 h 20 after QR 3536 arrives on the timetable: more than half a day, so not a connection we count.