QR 3543 then FR 149 at Barcelona
Bilbao → Barcelona → Berlin
Timetable, Barcelona time
21:05QR 3543 from Bilbao at the gate
14:20FR 149 to Berlin leaves the gate
17 h 15 apart on the timetable, overnight
FR 149 leaves 17 h 15 after QR 3543 arrives on the timetable: more than half a day, so not a connection we count.