QR 3593 then EC 7153 at Barcelona
Logrono → Barcelona → Milan
Timetable, Barcelona time
13:00QR 3593 from Logrono at the gate
12:15EC 7153 to Milan leaves the gate
23 h 15 apart on the timetable, overnight
EC 7153 leaves 23 h 15 after QR 3593 arrives on the timetable: more than half a day, so not a connection we count.