QR 3672 then FR 867 at Barcelona
Berlin → Barcelona → Venezia
Timetable, Barcelona time
19:55QR 3672 from Berlin at the gate
09:45FR 867 to Venezia leaves the gate
13 h 50 apart on the timetable, overnight
FR 867 leaves 13 h 50 after QR 3672 arrives on the timetable: more than half a day, so not a connection we count.