QR 3674 then FR 6597 at Barcelona
Firenze → Barcelona → Manchester
Timetable, Barcelona time
11:35QR 3674 from Firenze at the gatealso IB 5371, LL 5371, VY 6071
10:25FR 6597 to Manchester leaves the gate
22 h 50 apart on the timetable, overnight
FR 6597 leaves 22 h 50 after QR 3674 arrives on the timetable: more than half a day, so not a connection we count.