QR 3686 then FR 133 at Barcelona
Catania → Barcelona → Berlin
Timetable, Barcelona time
16:10QR 3686 from Catania at the gate
07:40FR 133 to Berlin leaves the gate
15 h 30 apart on the timetable, overnight
FR 133 leaves 15 h 30 after QR 3686 arrives on the timetable: more than half a day, so not a connection we count.