QR 3692 then FR 149 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
17:05QR 3692 from Rome at the gate
14:20FR 149 to Berlin leaves the gate
21 h 15 apart on the timetable, overnight
FR 149 leaves 21 h 15 after QR 3692 arrives on the timetable: more than half a day, so not a connection we count.