QR 3714 then FR 6597 at Barcelona
Rome → Barcelona → Manchester
Timetable, Barcelona time
11:35QR 3714 from Rome at the gatealso IB 5331, LL 5331, VY 6001
10:25FR 6597 to Manchester leaves the gate
22 h 50 apart on the timetable, overnight
FR 6597 leaves 22 h 50 after QR 3714 arrives on the timetable: more than half a day, so not a connection we count.