SQ 387 then EC 7199 at Barcelona
Madrid → Barcelona → Edinburgh
Timetable, Barcelona time
11:15SQ 387 from Madrid at the gate
06:55EC 7199 to Edinburgh leaves the gate
19 h 40 apart on the timetable, overnight
EC 7199 leaves 19 h 40 after SQ 387 arrives on the timetable: more than half a day, so not a connection we count.