U2 2001 then FR 2507 at Barcelona
Manchester → Barcelona → Cologne
Timetable, Barcelona time
09:50U2 2001 from Manchester at the gate
22:20FR 2507 to Cologne leaves the gate
12 h 30 apart on the timetable
FR 2507 leaves 12 h 30 after U2 2001 arrives on the timetable: more than half a day, so not a connection we count.