UA 769 then FR 133 at Barcelona
Chicago → Barcelona → Berlin
Timetable, Barcelona time
13:15UA 769 from Chicago at the gatealso AC 4791, LH 8546
11:50FR 133 to Berlin leaves the gate
22 h 35 apart on the timetable, overnight
FR 133 leaves 22 h 35 after UA 769 arrives on the timetable: more than half a day, so not a connection we count.