V7 2164 then LA 5765 at Barcelona
Nantes → Barcelona → Firenze
Timetable, Barcelona time
20:10V7 2164 from Nantes at the gate
16:45LA 5765 to Firenze leaves the gate
20 h 35 apart on the timetable, overnight
LA 5765 leaves 20 h 35 after V7 2164 arrives on the timetable: more than half a day, so not a connection we count.