V7 2164 then LL 5026 at Barcelona
Nantes → Barcelona → Brussels
Timetable, Barcelona time
20:10V7 2164 from Nantes at the gate
19:00LL 5026 to Brussels leaves the gate
22 h 50 apart on the timetable, overnight
LL 5026 leaves 22 h 50 after V7 2164 arrives on the timetable: more than half a day, so not a connection we count.