IB 5857 then IB 424 at Barcelona
Manchester → Barcelona → Madrid
Timetable, Barcelona time
23:10IB 5857 from Manchester at the gatealso LL 5857, VY 7757, BA 8107
21:15IB 424 to Madrid leaves the gatealso IB 424S, LA 1589, LL 3024, VY 5100, AY 5576, AV 6173, BA 7084, QR 8067
22 h 05 apart on the timetable, overnight
IB 424 leaves 22 h 05 after IB 5857 arrives on the timetable: more than half a day, so not a connection we count.