W4 3563 then FR 867 at Barcelona
Arad → Barcelona → Venezia
Timetable, Barcelona time
19:35W4 3563 from Arad at the gate
09:45FR 867 to Venezia leaves the gate
14 h 10 apart on the timetable, overnight
FR 867 leaves 14 h 10 after W4 3563 arrives on the timetable: more than half a day, so not a connection we count.