W4 6021 then FR 133 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
14:30W4 6021 from Rome at the gate
11:50FR 133 to Berlin leaves the gate
21 h 20 apart on the timetable, overnight
FR 133 leaves 21 h 20 after W4 6021 arrives on the timetable: more than half a day, so not a connection we count.