W4 6833 then FR 7543 at Barcelona
Torino → Barcelona → Manchester
Timetable, Barcelona time
12:30W4 6833 from Torino at the gate
11:35FR 7543 to Manchester leaves the gate
23 h 05 apart on the timetable, overnight
FR 7543 leaves 23 h 05 after W4 6833 arrives on the timetable: more than half a day, so not a connection we count.