W4 6833 then LS 804 at Barcelona
Torino → Barcelona → Manchester
Timetable, Barcelona time
12:30W4 6833 from Torino at the gate
12:00LS 804 to Manchester leaves the gate
23 h 30 apart on the timetable, overnight
LS 804 leaves 23 h 30 after W4 6833 arrives on the timetable: more than half a day, so not a connection we count.