AV 8395 then LA 4216 at Bogotá
Quito → Bogota → Cucuta
Timetable, Bogota time
05:10AV 8395 from Quito at the gate
04:25LA 4216 to Cucuta leaves the gate
23 h 15 apart on the timetable, overnight
LA 4216 leaves 23 h 15 after AV 8395 arrives on the timetable: more than half a day, so not a connection we count.