AV 8596 then 9R 8658 at Bogotá
Cali → Bogota → Puerto Asis
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
04:559R 8658 to Puerto Asis leaves the gate
12 h 25 apart on the timetable, overnight
9R 8658 leaves 12 h 25 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.