AV 8596 then AR 8916 at Bogotá
Cali → Bogota → Medellín
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
13:35AR 8916 to Medellín leaves the gate
21 h 05 apart on the timetable, overnight
AR 8916 leaves 21 h 05 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.