AV 8596 then JA 5112 at Bogotá
Cali → Bogota → Medellín
Timetable, Bogota time
16:30AV 8596 from Cali at the gate
05:00JA 5112 to Medellín leaves the gate
12 h 30 apart on the timetable, overnight
JA 5112 leaves 12 h 30 after AV 8596 arrives on the timetable: more than half a day, so not a connection we count.